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Place popcorn in a large mixing bowl and set aside. Lay out waxed paper on table and lightly spray with cooking spray.
In a medium saucepan, combine sugar, corn syrup, butter, cocoa and salt.
Over medium heat, stir occasionally until butter is melted and all is combined. Continue cooking and bring to a boil. Don't forget to stir. Continue cooking for about 2 minutes. You want the temperature, if you're using a candy thermometer to reach 230, soft ball stage. Remove from heat and add vanilla.
Pour over popcorn and toss to coat evenly.
Spread out on waxed paper and separate as best you can. This is a sticky popcorn and if you don't separate immediately, you'll have to break it after it hardens.
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